کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1411492 1501863 2009 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis and characterization of [1,2,3]-triazole containing liquid crystals through click reaction
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Synthesis and characterization of [1,2,3]-triazole containing liquid crystals through click reaction
چکیده انگلیسی

Two series of heterocyclic liquid crystalline compounds with [1,2,3]-triazole ring at the terminal position were synthesized and analyzed for mesomorphic properties and its characteristics. Heterocyclic triazole core was introduced in to the target compound through click reaction between aromatic phenolic azide and alkyl propargyl ethers. The structure of the target compounds and intermediates was conformed by the 1H NMR, 13C NMR and IR spectral techniques. All the compounds in both the series were exhibited thermotropic liquid crystalline mesophase. These compounds show enantiotropic Smectic A phase on heating and cooling experiments. This was further confirmed using differential scanning calorimetric investigations. Interestingly, earlier reports on non-polar alkyl group attached to [1,2,3]-triazole heterocyclic ring was not showing any liquid crystalline properties but in the present investigation introduction of polar alkoxy group very near to [1,2,3]-triazole heterocyclic ring displayed liquid crystalline properties.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 927, Issues 1–3, 18 June 2009, Pages 7–13
نویسندگان
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