کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1411507 | 1501863 | 2009 | 10 صفحه PDF | دانلود رایگان |
Four divalent cadmium coordination polymers, incorporating isomers of the hydrogen bonding capable diimine bis(pyridylmethyl)piperazine, have been prepared via solvent diffusion methods. Single crystal X-ray diffraction studies revealed both nitrogen donor disposition and anion dependence on dimensionality and topology. {[Cd(H2O)4(4-bpmp)](ClO4)2 · (4-bpmp) · 4H2O}n (1, 4-bpmp = bis(4-pyridylmethyl)piperazine) exhibits cationic 1-D [Cd(H2O)4(4-bpmp)]n2n+ chains that aggregate via extensive hydrogen bonding. {[Cd(3-bpmp)3(H2O)2](ClO4)2·5H2O}n (2, 3-bpmp = bis(3-pyridylmethyl)piperazine) manifests 1-D coordination polymer chains with curled, pendant monodentate 3-bpmp ligands. {[Cd(H2O)4(4-bpmp)]2[Cd(H2O)3(SO4)(4-bpmp)][Cd(H2O)2(SO4)2(4-bpmp)]·10H2O}n (3) displays sets of cationic [Cd(H2O)4(4-bpmp)]n2n+ chains, neutral [Cd(H2O)3(SO4)(4-bpmp)]n chains and anionic [Cd(H2O)2(SO4)2(4-bpmp)]n2n- chains linked into a pseudo 3-D lattice via numerous hydrogen bonding interactions. {CdSO4(H2O)3(3-bpmp)0.5]n (4) possesses a 2-D layered structure in which cadmium ions are connected by bridging 3-bpmp tethers and ligated sulfate ions. All four coordination polymers undergo blue–violet luminescence upon exposure to ultraviolet light.
Journal: Journal of Molecular Structure - Volume 927, Issues 1–3, 18 June 2009, Pages 101–110