کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1411936 1501909 2007 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis, crystal structure and characterization of a new zinc phthalocyanine complex
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آلی
پیش نمایش صفحه اول مقاله
Synthesis, crystal structure and characterization of a new zinc phthalocyanine complex
چکیده انگلیسی

A new complex [ZnPc(H2O)]·2DMF (1), where Pc = phthalocyanine and DMF = N,N-dimethylformamide, has been synthesized and its crystal has been determined by single-crystal X-ray diffraction method. The compound crystallizes in the triclinic space group P − 1. The lattice parameters are a = 11.668(5) Å, b = 12.186(5) Å, c = 13.939(6) Å, α = 78.697(7)°, β = 88.045 (7)°, γ = 62.949(7)°, V = 1727.4(12) Å3 and Z = 2. The Zn(II) ion is five-coordinated by four nitrogen atoms from Pc ligands and one oxygen atom from one water molecule. Notably, there are strong π–π interactions between Pc ligands, leading to 1D superamolecular structure. Moreover, the elemental analyses, FT-IR, UV–vis and Fluorescence spectra for this complex were also determined.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Structure - Volume 827, Issues 1–3, 17 February 2007, Pages 149–154
نویسندگان
, , , , , ,