کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1445741 | 988586 | 2013 | 12 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Nanoconfinement significantly improves the thermodynamics and kinetics of co-infiltrated 2LiBH4–LiAlH4 composites: Stable reversibility of hydrogen absorption/resorption Nanoconfinement significantly improves the thermodynamics and kinetics of co-infiltrated 2LiBH4–LiAlH4 composites: Stable reversibility of hydrogen absorption/resorption](/preview/png/1445741.png)
A uniformly distributed composite of 2LiBH4–LiAlH4 was successfully nanoconfined in mesoporous carbon scaffolds by using the solvent-mediated infiltration technique. The onset dehydrogenation temperatures of LiAlH4 and LiBH4 in the infiltrated 2LiBH4–LiAlH4 composite are decreased to ∼80 and ∼230 °C, respectively, and are 40 and 145 °C lower for their post-milled counterparts. Isothermal measurements reveal that ∼10 wt.% H2 could be released from the nanoconfined 2LiBH4–LiAlH4 composite at 300 °C within 300 min, while less than 4 wt.% H2 was released with respect to the post-milled mixture, even at 350 °C. Moreover, by taking advantage of both nanoconfinement and thermodynamic destabilization, the release of toxic diborane from LiBH4 was successfully suppressed. The dehydrogenation mechanism reveals that, under the structure-directing effects of carbon supports, the decomposition of the well-distributed 2LiBH4–LiAlH4 composite favors the formation of AlB2 instead of the thermodynamically stable Li2B12H12, which has been verified to play a crucial role in enhancing the hydrogenation of the 2LiBH4–LiAlH4 composite. In combination with the extra LiH supplied by the in situ decomposition of nanoconfined LiAlH4, the thus-tailored thermodynamics and kinetics of the 2LiBH4–LiAlH4 composite endow it with significantly advanced reversible hydrogen storage properties, with a stable reversibility without apparent degradation after seven dehydrogenation/rehydrogenation cycles.
Journal: Acta Materialia - Volume 61, Issue 18, October 2013, Pages 6882–6893