کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1447130 988636 2011 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Improving the wettability of aluminum on carbon nanotubes
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Improving the wettability of aluminum on carbon nanotubes
چکیده انگلیسی

The wetting of a metal on carbon nanotubes is fundamentally difficult due to the unusually large difference between their surface tensions and is a bottleneck for making metal–carbon nanotube (CNT) composites. Here, we report a simple method to enhance the wettability of metal particles on the CNT surface by applying aluminum, which is the material with the largest surface tension. This method involves two steps: (i) Al nanoparticles are decorated on multiwalled carbon nanotubes by electroplating and (ii) Al powder is further spread on Al-electroplated CNTs, followed by high-temperature annealing to accommodate complete wetting of the aluminum. The large surface tension difference is overcome by forming strong AlC covalent bonds initiated by defects of the CNTs. The decrease in the D-band intensity, the G-band shift in the Raman spectroscopy and the formation of AlC covalent bonds, as confirmed by X-ray photoelectron spectroscopy, were in agreement with our structural model of CNTvacancyOAl determined by density functional calculations.

Research highlights
► The wettability of CNT in Al metal was improved by electroplating method.
► This involves two steps: (i) Al electroplating and (ii) additional Al wetting.
► The large surface tension difference was overcome by forming Al—C covalent bonds.
► Al—C covalent bond was verified by Raman spectroscopy and XPS.
► Density functional calculations confirmed structural model of CNT—vacancy—O—Al.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Acta Materialia - Volume 59, Issue 9, May 2011, Pages 3313–3320
نویسندگان
, , , , , , ,