کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1450216 988727 2007 11 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Improved Cr2O3 adhesion by Ce ion implantation in the presence of interfacial sulfur segregation
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد سرامیک و کامپوزیت
پیش نمایش صفحه اول مقاله
Improved Cr2O3 adhesion by Ce ion implantation in the presence of interfacial sulfur segregation
چکیده انگلیسی

As-polished and preoxidized Ni–20Cr alloys were Ce-implanted with a dosage of 1 × 1017 ions/cm2, then subsequently oxidized at 1050 °C in air. The oxide adhesion and the extent of sulfur segregation at the oxide–alloy interface were determined, respectively, using tensile pull testing and scanning Auger microscopy with an in situ scratch device. The critical load for oxide failure was the lowest on the unimplanted Ni–20Cr, and was slightly higher on those with implantation made into a preformed oxide. Oxides that formed directly on Ce-implanted Ni–20Cr never failed under the pull test, which showed the strongest scale adhesion; however, similar amounts of interfacial sulfur, which segregated from the alloy during oxidation, were found at all interfaces. Ce additions were also found to reduce the oxidation rate and affect the extent of voids at the scale–alloy interface. It is suggested that the change in the oxide growth mechanism reduces the number of interfacial voids and, unlike Al2O3, these factors are more important for Cr2O3 scale adhesion than sulfur segregation to the scale–alloy interface.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Acta Materialia - Volume 55, Issue 2, January 2007, Pages 443–453
نویسندگان
, ,