کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
148412 456411 2013 11 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Selective engineering using Mg–Al calcined hydrotalcite and microwave irradiation in mono-transesterification of diethyl malonate with cyclohexanol
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Selective engineering using Mg–Al calcined hydrotalcite and microwave irradiation in mono-transesterification of diethyl malonate with cyclohexanol
چکیده انگلیسی


• Synergism between microwave irradiation and solid base catalysis.
• Mono-transesterification of diethyl malonate with cyclohexanol Mg–Al calcined hydrotalcite.
• Microwave irradiation showed more than threefold increase vis-a-vis conventional heating.
• 69% conversion with 98% selectivity for cyclohexyl ethyl malonate at 100 °C in 2 h.
• Full catalyst characterization and theoretical analysis to develop kinetic model.

Selectivity engineering aspects of synergism between microwave irradiation and solid base catalysis is investigated for a highly selective mono-transesterification of diethyl malonate with cyclohexanol using Mg–Al calcined hydrotalcite as catalyst. Microwave irradiation showed threefold increase in cyclohexanol conversion vis-a-vis conventional heating and only the mono-transesterified product was obtained. The catalyst was characterised by XRD, FT-IR, CO2-TPD, surface area and pore size analysis. Hydrotalcite with Mg:Al composition as 3:1 gave the best results. Effect of various parameters was studied on conversion and selectivity. Under optimised reaction conditions, 69% conversion with 98% selectivity for cyclohexyl ethyl malonate was obtained for catalyst loading of at 100 °C in 2 h. The catalyst showed excellent reusability. Complete theoretical and experimental analysis has been done to develop a kinetic model for the reaction.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Journal - Volume 230, 15 August 2013, Pages 547–557
نویسندگان
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