کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1489438 | 992307 | 2011 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Effect of organic acid on the electrochemical properties of Li4Ti5O12/C composite powders synthesized by spray pyrolysis Effect of organic acid on the electrochemical properties of Li4Ti5O12/C composite powders synthesized by spray pyrolysis](/preview/png/1489438.png)
A composite powder of Li4Ti5O12 and carbon (LTO/C) was synthesized by spray pyrolysis using an aqueous solution of Li and Ti with an organic acid. As-prepared LTO/C particles had spherical morphology and nonaggregation characteristics. They also had a particle size of approximately 1 μm with a broad size distribution. As-prepared LTO/C powders were crystallized to have a spinel structure. The addition of lactic acid was most effective for improving the electrochemical properties of LTO/C. The rechargeable capacity of the LTO/C anode obtained from lactic acid was 164 mAh/g at 1 C. The retention was 96% after 100 cycles at 1 C. The rechargeable capacity of the LTO/C anode decreased with an increasing charge rate. The rechargeable capacity of LTO/C obtained from lactic acid was 150 mAh/g at 10 C. The cycle performance of the LTO/C anode obtained from lactic acid also had a high stability at 50 °C.
A composite powder of Li4Ti5O12 and carbon was synthesized by spray pyrolysis using an aqueous solution with an organic acid and exhibited an excellent rechargeable rate performance.Figure optionsDownload as PowerPoint slideHighlights
► The rechargeable properties of LTO/C anode were influenced by adding the carbon sources.
► LTO/C anode obtained from lactic acid showed highest rechargeable capacity among the organic acid used.
► LTO/C anode prepared by spray pyrolysis exhibited an excellent rechargeable rate performance compared to carbon-coated LTO.
Journal: Materials Research Bulletin - Volume 46, Issue 6, June 2011, Pages 796–800