کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
150618 | 456453 | 2011 | 12 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Oxidation of Cationic Red X-GRL by ozonation combined with UV radiation in aqueous solution: Degradation, kinetics, and modeling Oxidation of Cationic Red X-GRL by ozonation combined with UV radiation in aqueous solution: Degradation, kinetics, and modeling](/preview/png/150618.png)
O3/UV oxidation of Cationic Red X-GRL was investigated in a semi-batch column reactor under various operating conditions. The absorption of ozone into aqueous solution and subsequent oxidation of Cationic Red X-GRL can be described by an irreversible second order reaction kinetic model. The relative contributions of direct ozone oxidation and OH-facilitated indirect oxidation of the dyestuff was quantified, and the overall reaction rate constant and the kinetic regime were determined by interpreting the experimental data with a newly derived kinetic model. A modified Arrhenius Equation as a function of T and pH was obtained with an activation energy of 15.31 kJ mol−1 and exponential constant of 0.0093. The Hatta number of the reaction ranges from 0.041 to 0.085, indicating that the reaction occurs in the slow kinetic regime. A mechanistically sounder model was derived to describe the reaction kinetics, which takes into account mass transfer, ozone decomposition mechanisms, photolysis, and Cationic Red X-GRL degradation pathways. The model was able to adequately interpret the measured concentrations of Cationic Red X-GRL, dissolved ozone, off gas ozone, hydroxyl peroxide, and nitrate. Furthermore, a model-based sensitivity analysis of concentrations and ratios of O3/UV system were performed with respect to various model parameters.
Journal: Chemical Engineering Journal - Volume 171, Issue 2, 1 July 2011, Pages 628–639