کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
150668 456455 2011 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Kinetics of phenol hydrogenation over Pd-containing hypercrosslinked polystyrene
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Kinetics of phenol hydrogenation over Pd-containing hypercrosslinked polystyrene
چکیده انگلیسی

Hypercrosslinked polystyrene (HPS) has been used as a support for preparation of the palladium-based catalyst, Pd/HPS, for gas phase hydrogenation of phenol to cyclohexanone. At the phenol conversion 99%, the catalyst provides selectivity for ketone not lower than 95 mol%. The Pd/HPS catalyst showed high stability, retaining its catalytic performance at least for 20 days. Kinetics was used to compare Pd/HPS with the commercial Pd/Al2O3 catalyst. The catalytic efficiency was assessed using the derived dimensionless kinetic equation without a ‘time’ parameter. Three major reaction routes with their rate parameters and activation energies were revealed. From kinetic parameters, the maximum possible yield of cyclohexanone in the temperature range of 120–180 °C was determined. The important feature of the Pd/HPS catalyst is that selectivity is independent of the temperature at a certain phenol conversion. At elevated temperatures (160–180 °C), the selectivity is at least 2–3% higher as compared to the commercial catalyst Pd/Al2O3, which makes Pd/HPS largely promising for industrial applications.


► Hypercrosslinked polystyrene as a support for Pd/HPS catalyst.
► Phenol selectivity for cyclohexanone not lower than 95 mol% at the conversion 99%.
► Selectivity is independent of the temperature.
► Kinetics is used to compare Pd/HPS with the commercial Pd/Al2O3 catalyst.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Journal - Volumes 176–177, 1 December 2011, Pages 33–41
نویسندگان
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