کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1543528 | 1512868 | 2016 | 10 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Thermoelectric properties of nano-granular indium–tin-oxide within modified electron filtering model with chemisorption-type potential barriers Thermoelectric properties of nano-granular indium–tin-oxide within modified electron filtering model with chemisorption-type potential barriers](/preview/png/1543528.png)
• Improved electron filtering model (EFM) with potential barriers (PB) was considered.
• Inelastic scattering of electrons was taken into account within EFM.
• Spatial criteria for EFM applicability was revealed.
• Improved thermoelectric parameters for ITO with PB within EFM were found.
• Chemisorption nature of PB for nanoscale ITO was considered and found as appropriate.
In this work, an approach to the numerical study of the thermoelectric parameters of nanoscale indium tin oxide (ITO, Sn content<10 at%) based on an electron filtering model (EFM) was developed. Potential barriers at grain boundaries were assumed to be responsible for a filtering effect. In the case of the dominant inelastic scattering of electrons, the maximal distance between potential barriers was limited in this modified model. The algorithm for such characteristic length calculation was proposed, and its value was evaluated for ITO. In addition, the contributions of different scattering mechanisms (SMs) in electron transport were examined. It was confirmed that in bulk ITO, the scattering on polar optical phonons (POPs) and ionized impurities dominates, limiting electron transport. In the framework of the filtering model, the basic thermoelectric parameters (i.e., electrical conductivity, mobility, Seebeck coefficient, and power factor (PF)) were calculated for ITO in the temperature range of 100–500 °C as a function of potential barrier height. The results demonstrated a sufficient rise of the Seebeck coefficient with an increase in barrier height and specific behavior of PF. It was found that PF is very sensitive to barrier height, and at its optimal value for granular ITO, it may exceed the PF for bulk ITO by 3–5 times. The PF maximum was achieved by band bending, slightly exceeding Fermi energy. The nature of surface potential barriers in nano-granular ITO with specific grains is due to the oxygen chemisorption effect, and this can be observed despite of the degeneracy of the conduction band (CB). This hypothesis and the corresponding calculations are in good agreement with recent experimental studies [Brinzari et al. Thin Solid Films 552 (2014) 225].
Journal: Physica E: Low-dimensional Systems and Nanostructures - Volume 81, July 2016, Pages 49–58