Synthesis and characterization of Fe-doped β-Bi2O3 porous microspheres with enhanced visible light photocatalytic activity

• Porous Fe-doped β-Bi2O3 microspheres were synthesized by hydrothermal and thermal treatment method.
• Fe-doped Bi2O3 microspheres demonstrated strong absorbance in the range of 420–600 nm.
• β-Bi2O3 microspheres doped with 4% Fe shows outstanding visible-light photocatalytic activity than pure β-Bi2O3.
• An appropriate amount of Fe3+ ions can act as intermediates for photo-generated holes and electrons transfer.

Fe-doped β-Bi2O3 porous microspheres (Fe–Bi2O3) were fabricated by a facile hydrothermal method. The structures, morphology and optical properties of Fe–Bi2O3 samples were characterized by X-ray powder diffraction (XRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) and UV–vis diffuse reflectance spectroscopy. The results from XRD analysis confirmed that a completed thermal conversion of the precursors to Fe doped β-Bi2O3 at the temperature of 375 °C. The iron ions is substitution for Bi3+ in the Bi2O3 lattice structure with the presence of Fe3+, which proved by the XPS. The SEM observations exhibited that the morphology of the as-prepared photocatalysts was porous microspheres. According to the results of UV–vis spectra, the Fe-doped β-Bi2O3 microspheres demonstrated a strong visible-light absorbance in the wavelength range of 420–600 nm. Under visible light irradiation (λ > 420 nm), Fe-doped β-Bi2O3 photocatalysts with the content of 4 mol% displayed highest photocatalytic activity for the Methyl Orange (MO) photodegradation. The mechanism for the enhanced photocatalytic activity of Fe-doped β-Bi2O3 photocatalysts was also proposed.

Figure optionsDownload as PowerPoint slide