کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1613362 1005597 2013 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Hydrogen absorption and diffusivity in ZnO single crystals
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
Hydrogen absorption and diffusivity in ZnO single crystals
چکیده انگلیسی

ZnO single crystals electrochemically charged with hydrogen were characterized. The concentration of hydrogen introduced into the crystals was determined by nuclear reaction analysis and was found to be in a reasonable agreement with the value estimated from the Faraday’s law. Moreover, a sub-surface layer with very high concentration of hydrogen and very high density of open-volume defects was formed by plastic deformation caused by hydrogen-induced stress. Specific surface modification caused by hydrogen-induced slip in the c-direction was observed on hydrogen loaded crystals. Hydrogen diffusion coefficient in ZnO was estimated by in situ electrical resistivity measurement. It was found that hydrogen diffusion in the c-direction is faster than in the a-direction most probably due to open channels existing in the wurtzite structure along the c-axis.


► Hydrothermally grown ZnO crystals were electrochemically doped with hydrogen.
► Depth profile of hydrogen concentration introduced into the crystal was determined.
► Hydrogen loading created sub-surface region with high hydrogen concentration.
► Hydrogen-induced plastic deformation causes specific surface modification.
► Hydrogen diffusion in ZnO is faster in the c-direction than in the a-direction.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Alloys and Compounds - Volume 580, Supplement 1, 15 December 2013, Pages S51–S54
نویسندگان
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