کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1613372 | 1005597 | 2013 | 4 صفحه PDF | دانلود رایگان |
• New hydrides of alloys previously considered as nonhydride-forming were obtained.
• New phase transitions of hydrides at high pressure were found.
• New materials for metal-hydride compressors were identified.
The paper presents a review of the recent work done in MSU on intermetallic hydrides with high dissociation pressure. Hydrogen sorption properties of a large variety of AB5, AB2 and BCC intermetallic compounds and alloys were studied at pressures up to 3000 atm. Several new intermetallic hydrides with potential application in high-capacity hydrogen storage devices have been identified for the first time and fully characterised using a gas-volumetric analytical technique in a unique high-pressure apparatus. Basing on the experimental and literature results the relationships between hydrogen absorption capacity, thermodynamic parameters of interaction and composition of alloys were established. Obtained results provide a good perspective for practical application of the studied hydrides especially in metal-hydride compressors.
Journal: Journal of Alloys and Compounds - Volume 580, Supplement 1, 15 December 2013, Pages S90–S93