کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1614918 | 1516340 | 2013 | 4 صفحه PDF | دانلود رایگان |

The epitaxial growth of CuInS2 thin films on single-crystal sapphire (0 0 0 1) substrates was first attempted by using pulsed laser deposition. A highly dense CuInS2 ceramic target with chalcopyrite structure was prepared by sintering high-purity (5N) powders in vacuum at 960 °C for an hour. CuInS2 thin films deposited at various temperatures all grew in a (1 1 2) preferred orientation, suggesting a three-dimensional island-like growth mechanism. When deposited at 700 °C, epitaxial growth of CuInS2 films on c-plane sapphire was achieved with an out-of-plane orientation of CuInS2 (1 1 2)|| sapphire (0 0 0 1) and in-plane orientation of CuInS2[1¯10]‖sapphire(101¯0). A typical rocking curve half width of 0.17° demonstrates a high degree of crystallinity as well as excellent alignment of the CuInS2 films along [2 2 1], whereas in-plane two domains rotated by 180° with respect to each other are found coexisting in the epilayers. High-quality epitaxial thin films will allow further research into the fundamental properties of CuInS2 absorber layers, which will eventually help to improve conversion efficiencies of CuInS2-based solar cells.
► A highly dense CuInS2 ceramic target with chalcopyrite structure was sintered in high vacuum.
► Epitaxial growth of CuInS2 thin films on sapphire (0 0 0 1) substrates was achieved by PLD at 700 °C.
► Epitaxial relationship is CuInS2 (1 1 2)|| sapphire (0 0 0 1) while CuInS2[1¯10]‖sapphire(101¯0).
► A rocking curve half width of 0.17° demonstrates an excellent out-of-plane ordering of the films.
► In-plane two domains rotated by 180° to each other are found coexisting in the epilayers.
Journal: Journal of Alloys and Compounds - Volume 553, 15 March 2013, Pages 282–285