کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1647655 1517321 2011 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Passivation of steel surface: An atomistic modeling approach aided with X-ray analyses
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد فناوری نانو (نانو تکنولوژی)
پیش نمایش صفحه اول مقاله
Passivation of steel surface: An atomistic modeling approach aided with X-ray analyses
چکیده انگلیسی

Using a quantum mechanics-based atomistic modeling approach and X-ray analyses, we explored the oxidation process of steel surface in a typical ambient condition. The growth of iron oxides on steel surface was found to be highly dependent on the thermodynamics and availability of reactants. Three oxidation stages were identified before the formation of a high-density triplex structure on steel surface, after which the oxidation of iron atoms progressed at a significantly reduced speed. Results from this atomistic study can be expected to improve the understanding of the passivation and depassivation of steel surface toward an effective control of iron corrosion.


► Oxidation of iron surface involves three stages with distinct oxidation speeds.
► Early iron oxidation is highly thermodynamic and involves many unstable species.
► A triplex structure formed on iron surface notably reduces the oxidation speed.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Letters - Volume 65, Issues 21–22, November 2011, Pages 3223–3226
نویسندگان
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