کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1694037 | 1519059 | 2016 | 10 صفحه PDF | دانلود رایگان |
• Beatrix rectorite is a 1:1 regular interstratification of mica and smectite.
• The expandable smectite layer has montmorillonite-beidellite composition.
• The dioctahedral mica phase is Na-Ca-rich, i.e. of paragonite-margarite series.
• XRF analysis indicates a 5:2 paragonite to margarite distribution.
Three rectorite samples from the Beatrix Gold Mine, South Africa were characterized. Scanning electron microscopy revealed a layered morphology. High resolution transmission microscopy showed well distinguished light and dark layers of about 2.20 nm consistent with the 1:1 interstratified mica-smectite nature. X-ray diffraction measurements confirmed the basal spacing d001 of 2.20 nm consistent with a one-water-layer structure. Unit cell parameters, for a monoclinic unit cell with primitive lattice, refined to a = 5.177 Å; b = 8.980 Å; c = 22.489 Å and β = 97.335° with mean crystallite size around 14 nm and calculated cell volume of 1045 Å3. The Greene-Kelly test suggested that the expandable smectite layers have montmorillonite-beidellite composition. Nuclear magnetic resonance spectroscopy indicated a high degree of Al substitution and the presence of two different Al sites corresponding to six- and four-fold octahedral and tetrahedral aluminum respectively. The chemical composition and diffraction data suggest that the mica is Na-Ca-rich, i.e. of paragonite-margarite series. The fixed interlayer regions (mica interlayers) contains proportionally dominant Na+ and Ca2 + and minor amounts of K+. The exchangeable smectitic interlayers contain almost equal amounts of Na+ and Ca2 + ions. The distribution of the interlayer Na+ ions was quantified by 23Na solid-state NMR spectroscopy. It points to a three component mixed-layer structure with considerable variation in the composition of the mica layer of the different samples.
Journal: Applied Clay Science - Volume 126, June 2016, Pages 7–16