کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1695751 | 1011874 | 2010 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
High-temperature X-ray powder diffraction as a tool for characterization of smectites, layered double hydroxides, and their intercalates with porphyrins
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
علوم زمین و سیارات
ژئوشیمی و پترولوژی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: High-temperature X-ray powder diffraction as a tool for characterization of smectites, layered double hydroxides, and their intercalates with porphyrins High-temperature X-ray powder diffraction as a tool for characterization of smectites, layered double hydroxides, and their intercalates with porphyrins](/preview/png/1695751.png)
چکیده انگلیسی
We have analyzed expandable clay minerals and layered double hydroxides with different interlayer ions by high-temperature X-ray powder diffraction (HT-XRD) with comparison to thermal analysis (DTG/DTA) coupled with evolved gas analysis (EGA). We described in detail their thermal behaviour with emphasis to the differences among samples related to their crystallochemical characteristics. Porphyrin-intercalated smectites have a quite unique thermal behaviour as monitored by HT-XRD; the intercalates with tetrakis(1-methyl-4-pyridinio)porphyrin have a basal spacing of about 1.4 nm and are thermally stable up to ca. 600 °C. The resolution of the individual dehydration steps of smectites (from 2-layer hydrate via 1-layer hydrate to the anhydrous form) is much better in HT-XRD then in DTG/EGA curves. Layered double hydroxides (LDHs) have a varying thermal stability depending on their chemical composition and crystallinity. LDHs intercalated with porphyrin anions are thermally stable up to 350-400 °C.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Clay Science - Volume 49, Issue 4, August 2010, Pages 363-371
Journal: Applied Clay Science - Volume 49, Issue 4, August 2010, Pages 363-371
نویسندگان
Anna PÃÅ¡ková, Petr BezdiÄka, David Hradil, Eva KáfuÅková, Kamil Lang, Eva VeÄernÃková, FrantiÅ¡ek Kovanda, TomáÅ¡ Grygar,