Thermal regeneration of sulfuric acid hydrates after irradiation

In an attempt to more completely understand the surface chemistry of the jovian icy satellites, we have investigated the effect of heating on two irradiated crystalline sulfuric acid hydrates, H2SO4·4H2O and H2SO4·H2O. At temperatures relevant to Europa and the warmer jovian satellites, post-irradiation heating recrystallized the amorphized samples and increased the intensities of the remaining hydrate’s infrared absorptions. This thermal regeneration of the original hydrates was nearly 100% efficient, indicating that over geological times, thermally-induced phase transitions enhanced by temperature fluctuations will reform a large fraction of crystalline hydrated sulfuric acid that is destroyed by radiation processing. The work described is the first demonstration of the competition between radiation-induced amorphization and thermally-induced recrystallization in icy ionic solids relevant to the outer Solar System.

► We investigated the effect of heating irradiated H2SO4·4H2O and H2SO4·H2O.
► Post-irradiation heating recrystallizes the samples and regenerates the original hydrates.
► Over geological times, the destroyed acid hydrates will be regenerated on the icy satellites.
► This is the first report of recrystallization in ionic solids relevant to the outer solar system.