کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
17873 | 42702 | 2009 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Lactones 32 [1]: New aspects of the application of Fusarium strains to production of alkylsubstituted ɛ-lactones
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بیو مهندسی (مهندسی زیستی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Lactones 32 [1]: New aspects of the application of Fusarium strains to production of alkylsubstituted ɛ-lactones Lactones 32 [1]: New aspects of the application of Fusarium strains to production of alkylsubstituted ɛ-lactones](/preview/png/17873.png)
چکیده انگلیسی
Wild strains Fusarium oxysporum and Fusarium avenaceum were chosen among six to the Baeyer–Villiger oxidation of alkylsubstituted cyclohexanones (1a–e) to the corresponding highly enantiomerically enriched ɛ-lactones. Besides the oxidation activity, the biocatalysts were also able to the reduction of carbonyl group. Only cis-methylcyclohexanols turned out to be further transformed to lactones. Biotransformations of optically enriched ketones and alcohols were also studied to give an overall view of stereoselectivity of the enzymes involved in biocatalytic pathway.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Enzyme and Microbial Technology - Volume 45, Issue 2, 7 August 2009, Pages 156–163
Journal: Enzyme and Microbial Technology - Volume 45, Issue 2, 7 August 2009, Pages 156–163
نویسندگان
Barbara Ratuś, Witold Gładkowski, Czesław Wawrzeńczyk,