کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1793132 | 1023666 | 2010 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Stabilities of crystal faces of anhydrite (CaSO4) compared by AFM observation of facet formation processes in aqueous solutions Stabilities of crystal faces of anhydrite (CaSO4) compared by AFM observation of facet formation processes in aqueous solutions](/preview/png/1793132.png)
Micro-facet formation processes were observed, with atomic force microscopy (AFM), at presumably less stable (0 1 1) and (1 1 1) faces of anhydrite (CaSO4) crystal in aqueous solutions containing either Ca2+ or SO42− ions. The order of relative stabilities of the crystal faces was (0 1 0)∼(1 0 0)>(1 1 1)>(0 1 1)≥(0 0 1). While (0 1 1), (0 1 0) and (1 1 1) faces were stabilized by either ions, (0 0 1) face was stabilized mainly by SO42− ions. Atom-resolved AFM images were observed in air for (0 1 1) and (1 1 1) faces after soaking in CaCl2 aq. (0.01 mol dm−3). At these faces, positive charges of Ca2+ at the outermost layers are partly cancelled by the negative charges of O atoms of the SO42− ions centered at lower levels. At (1 0 0) face, {1 1 1} ledges with bilayer height make growth or dissolution fronts around a screw dislocation. The relationship between natural crystal forms and chemical growth environment is discussed. Growth in sulfate-rich and Ca2+-rich conditions gives different crystal shapes.
Journal: Journal of Crystal Growth - Volume 312, Issue 4, 1 February 2010, Pages 573–579