کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1795772 1023729 2007 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Structural units of polycomponent melts modeled using diffraction, spectroscopy, and computation techniques
موضوعات مرتبط
مهندسی و علوم پایه فیزیک و نجوم فیزیک ماده چگال
پیش نمایش صفحه اول مقاله
Structural units of polycomponent melts modeled using diffraction, spectroscopy, and computation techniques
چکیده انگلیسی
Molten sodium salts were studied using in situ diffractiometry and Raman spectroscopy with the aim to establish the composition, arrangement, and tendencies in the temperature evolution of major structural units (SU). The obtained results agree well with the quantum-chemical calculations of the models of corresponding cation-anion associative complexes (AC). A conclusion is made that supports the interpretation of AC with a temperature-dependent association-dissociation constant as a high reactivity SU of polycomponent melts, in contrast with the passive ones, i.e., high-polycondensed fragments of anion groupings. The AC with the configuration predominant in precursor clusters as well as the structure-forming cations can be regarded as elementary crystal growth units. The NMR-spectroscopy of cesium-borate glasses suggests varying structural state and different effects of the structure-forming cations in the polycomponent systems.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Crystal Growth - Volume 303, Issue 1, 1 May 2007, Pages 44-48
نویسندگان
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