کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1815647 1025668 2009 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
EPR and optical absorption study of Cr3+-doped ammonium oxalate monohydrate single crystals
موضوعات مرتبط
مهندسی و علوم پایه فیزیک و نجوم فیزیک ماده چگال
پیش نمایش صفحه اول مقاله
EPR and optical absorption study of Cr3+-doped ammonium oxalate monohydrate single crystals
چکیده انگلیسی

The electron paramagnetic resonance (EPR) study of the Cr3+-doped ammonium oxalate monohydrate (AOM) single crystal is done at room temperature. Two magnetically inequivalent sites for chromium are observed. The hyperfine structure for Cr53 isotope is also obtained. The spin Hamiltonian parameters are evaluated as: D=(309±2)×10−4 cm−1, E=(103±2)×10−4 cm−1, g=1.9820±0.0002, A=(161±2)×10−4 cm−1 for site I and D=(309±2)×10−4 cm−1, E=(103±2)×10−4 cm−1, g=1.9791±0.0002, A=(160±2)×10−4 cm−1 for site II, respectively. On the basis of EPR data the site symmetry of Cr3+ doped single crystal is discussed. The optical absorption spectra are recorded in 195–925 nm wavelength range at room temperature. The energy values of different orbital levels are determined. On the basis of EPR and optical data, the nature of bonding in the crystal is discussed. The values of different parameters are B=803, C=3531, Dq=2208 cm−1, h=0.59 and k=0.21, where B and C are Racah parameters, Dq is crystal field parameter and h and k are nephelauxetic parameters, respectively.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Physica B: Condensed Matter - Volume 404, Issue 1, 15 January 2009, Pages 82–88
نویسندگان
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