کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
183159 | 459537 | 2016 | 7 صفحه PDF | دانلود رایگان |
• Uniform hydrogen storage alloys supported on reduced graphite oxide were prepared.
• The top-down fabrication strategy of the composites is effective.
• HSAs/RGO hybrid electrodes show enhanced high-rate dischargeability performance.
• The mechanisms behind enhanced high-rate dischargeability performance are revealed.
The main challenge of applications of nickel metal hydride batteries in high power fields, new-energy vehicles, power tools, military devices, etc., originates from poor high-rate dischargeability of their negative electrode material—hydrogen storage alloys (HSAs). Here we report the design and synthesis of a composite by coating HSAs with reduced graphite oxide (RGO) via a top-down route. The capacity retention rate of the fabricated HSAs/RGO hybrid electrode reaches 51.25% at a discharge current density of 3000 mA g−1, which is almost 4 times that of bare HSAs electrode (13.51%). Such an enhanced high-rate dischargeability performance is caused by (1) high specific surface area of RGO to increase active sites; (2) high conductivity of RGO to accelerate the charge transfer rate; and (3) unique interconnected RGO sheets among HSAs to reduce the internal resistance.
In this work, we report a top-down route for preparation of uniform hydrogen storage alloys supported on reduced graphite oxide (HSAs/RGO). The as-prepared hybrid composites show enhanced high-rate dischargeability performance.Figure optionsDownload as PowerPoint slide
Journal: Electrochimica Acta - Volume 200, 10 May 2016, Pages 59–65