کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
184110 | 459568 | 2015 | 9 صفحه PDF | دانلود رایگان |
• BP bark-derived, N-doped porous carbon (BPC) was fabricated for supercapacitors.
• BPC was prepared by hydrothermal treatment followed by pyrolysis and activation.
• The electrochemical tests exhibited a high specific capacitance of 320 F g−1.
• Retention of 94% of its initial capacitance was achieved after 10000 cycles.
In this work, we present a facile approach to synthesize nitrogen-doped porous carbon materials via a two-step fabrication process using the stem bark of broussonetia papyrifera (BP) as the biomass precursor. Firstly, the BP stem bark is hydrothermally treated in a KOH aqueous solution. After filtration and drying, the hydrothermal product is directly subjected to simultaneous pyrolysis and activation, giving nitrogen-doped porous carbon materials. The morphology, structure and textural properties of the carbon materials are investigated by scanning electron microscopy, transmission electron microscopy, N2 sorption isotherms, and X-ray photoelectron spectroscopy. The obtained porous carbon exhibits a high BET surface area of 1212 m2 g−1 and an average pore size of 3.8 nm. Such porous carbon shows outstanding capacitive performance (320 F g−1 at 0.5 A g−1), good rate capacitive behavior, and excellent cycling stability due to the synergistic effect of N, O-doped species, indicating a great potential for supercapacitors.
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Journal: Electrochimica Acta - Volume 169, 1 July 2015, Pages 186–194