کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
184807 | 459582 | 2015 | 7 صفحه PDF | دانلود رایگان |
• The NiCo2S4 NTAs grown on nickel foam have been synthesized through a facile two-step hydrothermal method.
• The NiCo2S4 NTA electrode exhibits excellent performance for supercapacitors.
• This work highlights the importance of synthesis of nanotubular morphology for supercapacitors.
Ternary NiCo2O4 synthesized via annealing NiCo-precursor has been extensively studied as an advanced electrode material for high-performance supercapacitors. In this work, we demonstrate a facile hydrothermal synthesis of NiCo2S4 nanotube arrays (NTAs) by simply treating the NiCo-precursor with Na2S solution based on the Kirkendall effect. The NiCo2S4 NTAs grown on nickel foam substrate are directly evaluated as binder-free electrode for supercapacitors. Impressively, the NiCo2S4 NTA electrode delivers an ultrahigh capacitance of 15.58 F cm−2 at a current density of 10 mA cm−2, which is much higher than 3.63 F cm−2 of the mesoporous NiCo2O4 nanowire array (NWA) electrode. In addition, the NiCo2S4 NTA electrode also exhibits good cycling stability with 79.3% capacitance retention at high current density of 60 mA cm−2 after 2000 cycles. In view of the excellent electrochemical performance and the facile and cost-effective synthesis, such NiCo2S4 NTA electrode would hold great promise for high-performance supercapacitor applications in future.
The NiCo2S4 nanotube arrays (NTAs) grown on nickel foam substrate exhibits excellent electrochemical performance for high-performance supercapacitors.Figure optionsDownload as PowerPoint slide
Journal: Electrochimica Acta - Volume 151, 1 January 2015, Pages 35–41