Carbon cloth supported vanadium pentaoxide nanoflake arrays as high-performance cathodes for lithium ion batteries

• Construct a carbon cloth supported V2O5 nanoflake arrays.
• V2O5 nanoflake arrays show high Li-storage properties.
• Nanoflake arrays structure is favorable for fast ion and electron transfer

Carbon cloth supported vanadium pentoxide (V2O5) nanoflake arrays are synthesized by a facile solvothermal deposition method. The V2O5 nanoflakes grow quasi-vertically to the carbon cloth and show a star-fruit like hierarchical structure composed of 3 − 4 secondary flakes with a thickness of ∼20 nm. When applied as cathode material for lithium ion batteries, the V2O5 nanoflake arrays exhibit a high capacity of 292 mAh g−1 at 0.5 C, and 94% capacity (275 mAh g−1) retained after 100 cycles. In addition, the V2O5 nanoflakes present an impressive high-rate capability with 62% capacity (181 mAh g−1) retention when the rate changes from 0.5 C to 10 C. The noticeable electrochemical performances are mainly due to the carbon cloth supported thin nanoflake array structure, which provides fast ion/electron transfer, sufficient contact between active materials and electrolyte, and alleviates the structure degradation caused by volume expansion during the cycling process.

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