کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
185969 459605 2014 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
High Energy Density based Flexible Electrochemical Supercapacitors from Layer-by-Layer Assembled Multiwall Carbon Nanotubes and Graphene
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
High Energy Density based Flexible Electrochemical Supercapacitors from Layer-by-Layer Assembled Multiwall Carbon Nanotubes and Graphene
چکیده انگلیسی


• Layer-by-layer (LBL) assembly of MWCNTs and graphene.
• Thin film electrodes for high energy density based flexible supercapacitors.
• MWCNTs prevent the stacking of graphene sheets and also act as a conductive additive, spacer, and binder.
• The supercapacitor devices exhibit excellent cycling stability, retaining over 97% of its initial charge after 25,000 cycles.

Thin film electrodes for high energy density based flexible supercapacitors are fabricate using layer-by-layer (LBL) assembly of MWCNTs and graphene. The addition of conductive spacer of MWCNTs between the layers of graphene prevents the agglomeration between each other and therefore facilitates the maximum number of active sites for electrolyte ion intercalation. The supercapacitor devices based on this flexible LBL assembly show very high electrochemical capacitance (390 Fg−1) and exhibit excellent cycling stability, retaining over 97% of its initial charge after 25,000 cycles. The addition of MWCNTs between the layers of graphene raised the energy density by 31% and power density by 39% more than the bare graphene electrodes. The LBL films of MWCNTs-graphene yield ultra-high energy density of 168 Whkg−1 which is very promising for future potential application in high performance flexible energy storage devices.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 129, 20 May 2014, Pages 396–400
نویسندگان
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