کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
186029 | 459606 | 2014 | 6 صفحه PDF | دانلود رایگان |
• An actuator was developed using a CB/VGCF/IL gel electrode.
• PVdF(HFP)-based actuator electrochemical/electromechanical details were defined.
• An actuator generated a strain that surpassed that of SWCNT-based actuators.
• The displacement response frequency dependence was simulated using a kinetic model.
• A strain in the low-frequency limit and the response time constant were obtained.
The electrochemical and electromechanical properties of poly(vinylidene fluoride-co-hexafluoropropylene) based actuators using carbon black (CB)/vapor grown carbon fiber (VGCF)/ionic liquid (IL) composite gel electrodes formed without ultrasonication were compared with those of actuators using only CB or VGCF. The double-layer capacitance of the CB/VGCF/IL electrodes was larger than that of the CB/IL electrodes and increased with VGCF content. The amount of strain exhibited by the CB/VGCF/IL actuators was also larger than that for the CB/IL actuators, with the highest strain being produced for an actuator with a CB:VGCF ratio of 1:1. This was slightly larger than that for a polymer actuator using single-walled carbon nanotubes (SWCNTs), indicating that the proposed actuators exhibit sufficiently high performance for real-world applications without the need for expensive SWCNTs. Furthermore, the frequency dependence of the displacement response of the CB/VGCF/IL polymer actuators was successfully simulated using an electrochemical kinetic model similar to that for SWCNT-based actuators. The results yielded the strain in the low-frequency limit and the time constant of the response.
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Journal: Electrochimica Acta - Volume 123, 20 March 2014, Pages 340–345