کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
186336 459611 2014 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Initial stages of AZ91 Mg alloy micro-arc anodizing: Growth mechanisms and effect on the corrosion resistance
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Initial stages of AZ91 Mg alloy micro-arc anodizing: Growth mechanisms and effect on the corrosion resistance
چکیده انگلیسی


• The dielectric breakdown occurs for a specific value of capacitance.
• Before breakdown, Si is incorporated to the anodic film under MgSiO3 form.
• After breakdown, Si is incorporated to the anodic film also under Mg2SiO4 form.
• The presence of Mg2SiO4 in the anodic film provides good corrosion resistance due to sealing of the porosities.

In the framework of the new ecological regulations, micro-arc oxidation (MAO) appears as an alternative to usual processes in the field of corrosion protection of Mg alloys. In this work, the initial stages of anodic layer growth in KOH-based electrolytes are studied up to and beyond the initiation of the micro-arc regime.The properties of the first anodized film preceding the occurrence of the dielectric breakdown (corresponding to the start of the micro-arc regime) are mainly determined by the incorporation of additives (fluorides or silicates) in the film, as shown by in situ electrochemical measurements. Scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS) and micro-Raman spectroscopy reveal both the change of morphology and chemical state of silicate and fluoride in the anodized layer before and after the micro-arc regime. In terms of electrochemical behaviour, investigated by stationary methods and electrochemical impedance spectroscopy (EIS) in reference corrosive water, the anodic film grown in the silicate medium provides the best corrosion resistance thanks to a thick layer containing Mg2SiO4, whose degradation products seal the porosities of the coating.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 124, 1 April 2014, Pages 36–45
نویسندگان
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