The influence of boron dopant on the electrochemical properties of graphene as an electrode material and a support for Pt catalysts

• More defective sites in graphene after the doping of boron atoms.
• Fine dispersion of Pt nanoparticles supported on boron-doped graphene.
• Low electron transfer resistance at boron-doped graphene.
• High performance of boron-doped graphene as an electrode material or a support for Pt catalysts.

Boron-doped graphene (BGR) is prepared by thermal annealing of graphene oxide (GO) in the presence of boric acid. More defective sites are introduced into GR accompanied by the doping of boron. Low electron transfer resistance towards redox probe is observed at BGR. The BGR modified electrode can effectively distinguish the anodic peaks for ascorbic acid (AA), dopamine (DA), and uric acid (UA). The defective sites of BGR can also act as anchoring sites for the deposition of Pt nanoparticles. When used as a support for Pt electrocatalysts, Pt nanoparticles with an average diameter of 3.2 nm are deposited on BGR. The doping of boron into GR facilitates the dispersion of Pt nanoparticles and increases the utilization efficiency of Pt nanoparticles. The Pt/BGR exhibits significant catalytic activity towards the oxidation of methanol. The results demonstrate that BGR is a good support for Pt catalysts or an electrode material compared with the undoped GR.

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