کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
186603 | 459619 | 2013 | 6 صفحه PDF | دانلود رایگان |
• Organophilic vermiculite was prepared by ionic exchange reaction.
• Composite gel polymer electrolytes (CGPEs) were prepared by solution cast method.
• The introduction of organophilic vermiculite decreased the crystallinity of CGPE.
• Organophilic vermiculite contributed to an increase of ionic conductivity of CGPE.
• The electrochemical window of CGPE reached up to 3.8 V.
Organophilic vermiculite was prepared by ionic exchange reaction between vermiculite and cetyltrimethylammonium bromide, and it was then used as filler to prepare a series of composite gel polymer electrolytes containing poly(methyl methacrylate) and room temperature ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate. Surface morphology and structural nature of the composite electrolytes were examined by scanning electron microscopy and Fourier transform infrared spectroscopy, respectively. X-ray diffraction analysis confirmed that organophilic vermiculite decreased the crystallinity of polymer and formed intercalated polymer/layered silicate composite. On the other hand, the dispersion of organophilic vermiculite increased the thermal property of polymer electrolytes. Furthermore, the ionic conductivity and electrochemical window of composite gel polymer electrolyte reached up to the value of 4.01 × 10−3 S cm−1 and 3.8 V at the adding content of 8 wt.% organophilic vermiculite, respectively.
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Journal: Electrochimica Acta - Volume 111, 30 November 2013, Pages 108–113