کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
186869 | 459627 | 2013 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
An electrochemical quartz crystal microbalance study of poly(acrylonitrile) deposition initiated by electrogenerated superoxide
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
Poly(acrylonitrile) films were deposited electrochemically onto vitreous carbon electrodes from air-saturated acrylonitrile. Electrodeposition on gold was investigated with the use of an electrochemical quartz crystal microbalance (EQCM). It was found that the onset of deposition coincided with the reduction of dissolved oxygen at the electrode surface, indicating that the polymerisation reaction is initiated by the nucleophilic superoxide anion. The chemical composition of the film was confirmed by Raman spectroscopy. Such electrodeposited polymer films may have applications as polymer electrolytes for 3D microbattery applications.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 96, 30 April 2013, Pages 23–26
Journal: Electrochimica Acta - Volume 96, 30 April 2013, Pages 23–26
نویسندگان
Matthew J. Lacey, Maciej Sosna, John R. Owen,