کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
189621 | 459682 | 2011 | 6 صفحه PDF | دانلود رایگان |

In this study, we report the application of an inexpensive and easily prepared lead oxide–manganese oxide catalyst combined with Nafion (designated as Nf/PbMnOx) as a highly efficient air-cathode for a zinc–air battery. We verify the mechanistic study of the reduction of O2 for Nf/PbMnOx in alkaline aqueous solution using rotating ring/disk electrode voltammetry, and also an electrochemical approach using a wall-jet screen-printed ring disk electrode. The presence of Nf/PbMnOx shows great catalytic activity for the disproportionation reaction of HO2− to O2 and OH− with an overall 4e− reduction of O2 in the first reduction reaction. The 4e− reduction of O2 was eventually achieved at the Nf/PbMnOx through evidence from the slope of Koutecky–Levich plots. With these inherent features, we then fabricated the zinc–air battery with the Nf/PbMnOx catalyst and examine the performance for a practical application with air cathodes.
► We report a highly efficient air-cathode for a zinc–air battery.
► The lead oxide–manganese oxide catalyst combined with Nafion is inexpensive and easily prepared.
► The catalyst shows a catalytic activity for heterogeneous chemical disproportionation of HO2−.
Journal: Electrochimica Acta - Volume 56, Issue 17, 1 July 2011, Pages 6205–6210