کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
189821 | 459686 | 2011 | 10 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Electrochemical studies and self diffusion coefficients in cyclic ammonium based ionic liquids with allyl substituents Electrochemical studies and self diffusion coefficients in cyclic ammonium based ionic liquids with allyl substituents](/preview/png/189821.png)
Several cyclic ammonium-based ionic liquids (ILs) with allyl substituent are synthesized, these allyl substituent ILs have high ionic conductivity (up to 4.72 mS cm−1 at 30 °C) and wide electrochemical window of 5 V. The electrochemical behaviors of two organometallic redox couples Fc/Fc+ (ferrocene/ferrocenium) and Cc/Cc+ (cobaltocene/cobaltocenium) have been studied in these ILs, the calculated Stokes–Einstein product (Dη T−1) of ferrocene in ILs is larger than that of cobaltocenium in ILs. The self-diffusion coefficients of cation and anion in these ILs are studied using pulsed gradient spin-echo NMR technique. There are very few reports where electrochemically derived diffusion coefficients and self diffusion coefficients are available for comparison, so a new key concept in electrochemistry could be developed in this paper.
Research highlights
► Cyclic ammonium-based ionic liquids with allyl substituent have high conductivity.
► Ionic liquids with allyl substituent have wide electrochemical window.
► Electrochemical and self diffusion coefficients are available for comparison.
► The Stokes–Einstein plots of DT−1 vs. η−1 for redox couples in ILs are evaluated.
► Stokes–Einstein product of ferrocene is larger than that of cobaltocenium in ILs.
Journal: Electrochimica Acta - Volume 56, Issue 9, 30 March 2011, Pages 3209–3218