کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
189836 459686 2011 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Modeling of galvanostatic pulse and pulsed reverse electroplating of gold
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Modeling of galvanostatic pulse and pulsed reverse electroplating of gold
چکیده انگلیسی

A mathematical model of galvanostatic pulse and pulsed reverse electroplating of gold on a rotating disk electrode is presented. Using experimental polarization curves, dc current efficiencies, and literature-reported diffusion coefficients, model parameters are estimated. An accurate prediction of current efficiency by the on–off pulse-plating model was confirmed by experimental measurement. The current efficiency of pulse-reverse plating at relatively low waveform frequency is also successfully predicted, with less agreement at higher frequencies, presumably due to the simplified approach that the model employs to treat the complex set of reactions that occur during the anodic portion of the wave. When the reduction of adsorbed gold species produced during the oxidation portion of the pulse is included, improved agreement between experiment and theory is obtained.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 56, Issue 9, 30 March 2011, Pages 3328–3333
نویسندگان
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