کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
190722 459706 2010 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Studies based on the electrochemical response of 2-(2-nitrophenyl)-1H-benzimidazole at chemically modified electrodes with over-oxidized poly-1-naphthylamine
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Studies based on the electrochemical response of 2-(2-nitrophenyl)-1H-benzimidazole at chemically modified electrodes with over-oxidized poly-1-naphthylamine
چکیده انگلیسی

The development of a simple and efficient method to 2-(2-nitrophenyl)-1H-benzimidazole (NB) electrochemical determination using a polymer film coated chemically modified electrode is described. A glassy carbon (GC) electrode was modified employing an electro-polymerized film of 1-naphtylamine (1-NAP) followed by an over-oxidation treatment in 0.2 M sodium hydroxide solution (poly-1-NAPox electrode).The electrochemical behaviour of NB at the poly-1-NAPox electrode was investigated in a mixture of 10% ethanol + 90% buffer solution (pH 2) by cyclic voltammetry (CV) and square-wave voltammetry (SWV). The experimental results suggested that the poly-1-NAPox electrode had a good effect on NB electrochemical response because it avoided the electrode surface fouling as a consequence of the adsorption of NB reduction products, which was found when a bare GC electrode was employed as the working electrode. The NB cathodic current was dependent on the polymeric film over-oxidation degree (α).NB could be determined in the range from 2 × 10−6 to 5 × 10−5 M. The NB detection and quantification limits were 5 × 10−7 and 1.7 × 10−6 M, respectively. The percent relative standard deviation of the peak current to 10-replicated measurement using 1.2 × 10−5 M NB solution was 1.4%. The method showed to be rapid, simple and with a good sensitivity.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 55, Issue 15, 1 June 2010, Pages 4421–4427
نویسندگان
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