کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
191147 459715 2010 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
The electrochemical redox processes in methacrylate-based polymer electrolytes II. – Study on microelectrodes
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
The electrochemical redox processes in methacrylate-based polymer electrolytes II. – Study on microelectrodes
چکیده انگلیسی

The electrochemical behaviour of ferrocene was studied in different gel polymer electrolytes based on methyl, ethyl and 2-ethoxyethyl methacrylate and compared to the liquid aprotic solution (propylene carbonate). Voltammetric and chronoamperometric measurements on microelectrodes were conducted in order to describe the qualitative as well as quantitative behaviour of ferrocene in different conditions. Heterogeneous electron-transfer rate constants and diffusion coefficients of ferrocene in polymer electrolytes were estimated to be 1.1–7.8 × 10−3 cm s−1 and 4–13 × 10−8 cm2 s−1 depending on the electrolyte composition. The influence of the polymer polarity, ferrocene concentration and level of polymer cross-linkage on the kinetics of ferrocene oxidation and its transport was discussed. The electrolytes with poly(2-ethoxyethyl methacrylate) exhibit the highest ionic conductivity (2–4 × 10−4 S cm−1) as well as diffusion coefficient of ferrocene (1.3 × 10−7 cm2 s−1) in their structure.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 55, Issue 20, 1 August 2010, Pages 5911–5916
نویسندگان
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