Electrochemical corrosion characterization of Al–Ni alloys in a dilute sodium chloride solution

The aim of this study is to characterize the electrochemical corrosion resistance of Al–Ni alloy samples which were directionally solidified under upward unsteady state heat flow conditions. Electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization techniques were used to analyze the corrosion resistance in a dilute 0.05 M NaCl solution at 25 °C. Equivalent circuit analyses were also conducted. It was found that microstructural features such as the dendritic arrangement and the distribution of Al3Ni intermetallic particles have important roles on both the resulting pitting potential and the general corrosion resistance of Al–Ni alloys.