کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
191390 | 459721 | 2011 | 8 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Preparation of a high-performance Pt–Pd/C-electrocatalyst-coated membrane for ORR in PEM fuel cells via a combined process of impregnation and seeding: Effect of electrocatalyst loading on carbon support Preparation of a high-performance Pt–Pd/C-electrocatalyst-coated membrane for ORR in PEM fuel cells via a combined process of impregnation and seeding: Effect of electrocatalyst loading on carbon support](/preview/png/191390.png)
The influence of the electrocatalyst loading (2.0–40.7 wt.%) on a carbon support on its suitability as a cathode for proton-exchange membrane (PEM) fuel cells was evaluated at a constant membrane electrocatalyst loading of 0.15 mg/cm2. The results clearly demonstrate that different electrocatalyst loadings on a carbon support in the investigated range significantly affect not only the electrocatalyst activity but also the performance in H2/O2 fuel cells. Increasing the electrocatalyst loading on a carbon support led to an increase in the particle size of electrocatalyst and the pore size of the membrane electrode assembly (MEA) but a decrease in the particle size distribution and MEA thickness. The maximum oxygen-reduction reaction (ORR) activity and cell performance (745 mA/cm2 and 520 mW/cm2 at 0.6 V) were obtained at an electrocatalyst loading of 24.1 wt.% on a carbon support.
Journal: Electrochimica Acta - Volume 56, Issue 3, 1 January 2011, Pages 1164–1171