کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
191852 459730 2010 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
SiN/bamboo like carbon nanotube composite electrodes for lithium ion rechargeable batteries
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
SiN/bamboo like carbon nanotube composite electrodes for lithium ion rechargeable batteries
چکیده انگلیسی

A dual stage technique employing hot filament chemical vapor deposition (HFCVD) and radio frequency sputtering was used to synthesize SiN/BCNTs (bamboo like carbon nanotubes) on copper substrates. The films were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), Electron field emission studies (EFE), charge–discharge, and cyclic voltammetry. The comprehensive characterization is consistent with a nanolayer of amorphous SiN on BCNTs. Field emission experiments confirm the excellent contact of the SiN nanolayer with the surface of the BCNTs necessary for fabrication of a coin cell. Electrochemical testing shows that SiN/BCNT electrode can deliver an initial discharge capacity of 2000 mAh g−1 which is higher than the capacity of graphite and the reversible capacity after ten cycles is 300 mAh g−1. The cyclic voltammetry results suggest good reversibility with Li during cycling.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 55, Issue 7, 28 February 2010, Pages 2269–2274
نویسندگان
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