کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
192291 | 459738 | 2008 | 9 صفحه PDF | دانلود رایگان |

This paper presents a promising transparent counterelectrode system for a WO3 electrochromic device (ECD) on the basis of a stability-enhanced indium hexacyanoferrate (InHCF) electrode and a NaClO4/propylene carbonate (PC) electrolyte. Through SEM characterization it was found that clusters of granular InHCF nanoparticles (ca. 80–140 nm) were deposited on ITO substrates in HCl and KCl-stabilized plating solutions, and uniform micrometer thick films with high charge capacity could be obtained. From in situ electrochemical quartz crystal microbalance study, it was discovered that Na+ would enter or move out from the InHCF film in the “desolvated” form during the redox process in a PC electrolyte. Besides, NaClO4/PC resulted in higher electrochemical activity and reversibility than LiClO4/PC. With these discoveries, a durable WO3-InHCF ECD featuring blue-to-colorless electrochromism was fabricated successfully. The device remained 73.6 and 88.7% of its initial ΔT values at 600 and 800 nm after 40,000 rapid and successive coloring/bleaching cycles, respectively. Moreover, the cycling-induced loss of electrochromic performance almost completely restored after 1-month rest and kept unchanged for another month. Thus, the applicability of this nonaqueous InHCF counterelectrode system to ECDs was verified.
Journal: Electrochimica Acta - Volume 53, Issue 16, 30 June 2008, Pages 5306–5314