کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
192648 459748 2008 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Polymerisation occurrence in the anodic oxidation of phosphite on a boron-doped diamond electrode
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Polymerisation occurrence in the anodic oxidation of phosphite on a boron-doped diamond electrode
چکیده انگلیسی

The electrogeneration of polymeric phosphorus compounds during the anodic oxidation of aqueous solutions of phosphites on a boron-doped diamond electrode has been studied. Although the main oxidation product is orthophosphate, the results indicate the simultaneous generation of short-chain and cyclic compounds containing two and three phosphorus atoms whose evolution has been followed by ion chromatography.The effect on the reaction yield of several operative parameters such as current density, pH, temperature and initial phosphite concentration has been investigated.Consistently with the data presented, a new process for the generation of polymeric phosphates is obtained.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 53, Issue 15, 1 June 2008, Pages 4952–4957
نویسندگان
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