کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
192708 | 459750 | 2009 | 4 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Long-term cyclability of LiFePO4/carbon composite cathode material for lithium-ion battery applications Long-term cyclability of LiFePO4/carbon composite cathode material for lithium-ion battery applications](/preview/png/192708.png)
A simple high-energy ball milling combined with spray-drying method has been developed to synthesize LiFePO4/carbon composite. This material delivers an improved tap density of 1.3 g/cm3 and a high electronic conductivity of 10−2 to 10−3 S/cm. The electrochemical performance, which is especially notable for its high-rate performance, is excellent. The discharge capacities are as high as 109 mAh/g at the current density of 1100 mA/g (about 6.5C rate) and 94 mAh/g at the current density of 1900 mA/g (about 11C rate). At the high current density of 1700 mA/g (10C rate), it exhibits a long-term cyclability, retaining over 92% of its original discharge capacity beyond 2400 cycles. Therefore, the as-prepared LiFePO4/carbon composite cathode material is capable of such large-scale applications as hybrid and plug-in hybrid electric vehicles.
Journal: Electrochimica Acta - Volume 54, Issue 24, 1 October 2009, Pages 5656–5659