کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
193193 459764 2009 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Study of IrxRu1−xO2 oxides as anodic electrocatalysts for solid polymer electrolyte water electrolysis
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Study of IrxRu1−xO2 oxides as anodic electrocatalysts for solid polymer electrolyte water electrolysis
چکیده انگلیسی

Electrocatalysts of the general formula IrxRu1−xO2 were prepared using Adams’ fusion method. The crystallite characterization was examined via XRD, and the electrochemical properties were examined via cyclic voltammetry (CV) in, linear sweep voltammetry (LSV) and chronopotentiometry measurements in 0.5 M H2SO4. The electrocatalysts were applied to a membrane electrode assembly (MEA) and studied in situ in an electrolysis cell through electrochemical impedance spectroscopy (EIS) and stationary current density–potential relations were investigated. The IrxRu1−xO2 (x = 0.2, 0.4, 0.6) compounds were found to be more active than pure IrO2 and more stable than pure RuO2. The most active electrocatalyst obtained had a composition of Ir0.2Ru0.8O2. With an Ir0.2Ru0.8O2 anode, a 28.4% Pt/C cathode and the total noble metal loading of 1.7 mg cm−2, the potential of water electrolysis was 1.622 V at 1 A cm−2 and 80 °C.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 54, Issue 26, 1 November 2009, Pages 6250–6256
نویسندگان
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