کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
193640 459775 2009 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Simulations and study of electrochemical hydrogen energy conversion in EasyTest Cell
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Simulations and study of electrochemical hydrogen energy conversion in EasyTest Cell
چکیده انگلیسی

An EasyTest Cell concept is applied to study the performance characteristics of the electrochemical processor for polymer electrolyte membrane electrochemical hydrogen energy converters (PEM EHEC), broadly known as a membrane electrode assembly (MEA). A series of MEAs consisting of Nafion 117 polymer electrolyte and magnetron sputtered Pt, IrOx, and composite IrOx/Pt/IrOx catalysts with varying catalytic loadings were investigated. The partial electrode reactions proceeding in the real PEM EHEC, namely hydrogen oxidation (HOR), hydrogen evolution (HER), oxygen reduction (ORR), and oxygen evolution (OER), are simulated and studied in a recently developed test cell with a unitized gas compartment. The EasyTest Cell design gives possibilities for strict control of the experimental conditions by avoiding the usage of any auxilliary gas conditioning equipment. By varying the thickness of the sputtered Pt film, the catalyst loading is remarkably reduced (from 0.5 to 0.06 mg cm−2 or about 8 times) for both HOR and HER without any sacrifice of the electrode performance. The electrode with 0.2 mg cm−2 sputtered IrOx shows the best OER performance. The composite IrOx/Pt/IrOx electrode demonstrated a bi-functional catalytic activity toward both OER and ORR, as well as improved gas diffusion properties toward ORR compared to the single Pt layer with the same catalytic loading.A phenomenological criterion for evaluating the gas diffusion properties of the electrodes is proposed. The applied testing approach is validated via comparison of the results obtained in the EasyTestCell and the common laboratory PEM electrolytic cell.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 54, Issue 4, 30 January 2009, Pages 1269–1276
نویسندگان
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