کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
193683 | 459776 | 2007 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Study of neutral species coordination by macrocyclic anion receptors using FTIR spectroscopy
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Study of neutral species coordination by macrocyclic anion receptors using FTIR spectroscopy Study of neutral species coordination by macrocyclic anion receptors using FTIR spectroscopy](/preview/png/193683.png)
چکیده انگلیسی
Complexation ability for two various macrocyclic receptors applied previously as anion receptors to poly(ethylene oxide)-based solid polymer electrolytes was studied by means of FTIR spectroscopy. We have proved that the interactions between neutral species (solvent) and receptors depend both on the donor properties of the solvent and type of the functional groups in receptor. For solvent characterized by similar dielectric constant and coordinating properties (donor and acceptor numbers) like 1,2-dimethoxyethane and its high molecular weight analogues–poly(ethylene oxide) interactions are also affected by steric effect.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 53, Issue 4, 31 December 2007, Pages 1541–1547
Journal: Electrochimica Acta - Volume 53, Issue 4, 31 December 2007, Pages 1541–1547
نویسندگان
A. Sołgała, M. Kalita, G.Z. Żukowska,