کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
194197 459785 2008 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
The effect of the interlayer anions on the electrochemical performance of layered double hydroxide electrode materials
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
The effect of the interlayer anions on the electrochemical performance of layered double hydroxide electrode materials
چکیده انگلیسی

Both high energy density and high power density are vitally required for new applications such as electric vehicles. Here we present a comparison of two well-crystallised layered double hydroxides, [Ni4Al(OH)10]OH and [Ni4Al(OH)10]NO3, which shows that the former can maintain a better discharge capacity, 294–299 mAh g−1, than the latter, 233–287 mAh g−1 at a current density of 2000 mA g−1 within about 300 cycles, although both electrodes deliver a similar capacity of 326 mAh g−1 at 200 mA g−1 initially. It is believed that both the more watery interlayer space in [Ni4Al(OH)10]OH than in [Ni4Al(OH)10]NO3 and the morphologic changes induced by anion exchange of NO3− by OH− during electrochemical cycles play key roles in their behaviour.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 54, Issue 2, 30 December 2008, Pages 671–676
نویسندگان
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