کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
195747 459821 2007 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Room-temperature ionic liquids/multi-walled carbon nanotubes/chitosan composite electrode for electrochemical analysis of NADH
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Room-temperature ionic liquids/multi-walled carbon nanotubes/chitosan composite electrode for electrochemical analysis of NADH
چکیده انگلیسی

An electrochemical sensing platform was developed based on the integration of room-temperature ionic liquids (1-butyl-3-methylimidazolium tetrafluoroborate, BMIM·BF4) and multi-walled carbon nanotubes (MWNTs) with polymeric matrix (chitosan, CHIT). The resulting composite were investigated and characterized by FTIR, TEM, SEM, EDS and electrochemical methods. The BMIM·BF4/MWNTs/CHIT have good dispersibility in aqueous solution and can form a relative uniform film with unique structure. Electrochemical studies suggested that the BMIM·BF4/MWNTs/CHIT composite system provided a synergistic augmentation on the voltammetric and amperometric behaviors of electrochemical oxidation of NADH, which indicated by the decrease of the peak potential of NADH oxidation and the improvement of amperometric response. Additionally, the BMIM·BF4/MWNTs/CHIT/GC electrode shows good analytical performance such as low detection limit (0.06 μM), good regeneration and anti-fouling properties for determination of NADH. This nanomaterials-based composite may be used as electrochemical transducers and have potential application for designing a variety of NAD+-dependent electrochemical biosensors.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 52, Issue 24, 1 August 2007, Pages 6630–6637
نویسندگان
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