کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
195799 | 459821 | 2007 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: A novel lithium intercalation compound based on the layered structure of lithium nitridonickelates Li3−2xNixN A novel lithium intercalation compound based on the layered structure of lithium nitridonickelates Li3−2xNixN](/preview/png/195799.png)
New lithium nickel nitrides Li3−2xNixN (0.20 ≤ x ≤ 0.60) have been prepared and investigated as negative electrode in the 0.85/0.02 V potential window. These materials are prepared from a Ni/Li3N mixture at 700 °C under a nitrogen flow. Their structural characteristics as well as their electrochemical behaviour are investigated as a function of the nickel content. For the first time are reported here the electrochemical properties of a lithium intercalation compound based on a layered nitride structure. The Li3−2xNixN compounds can be reversibly reduced and oxidized around 0.5 V versus Li/Li+ leading to specific capacities in the range 120–160 mAh/g depending on the nickel content and the C rate. Due to a large number of lithium vacancies, the structural stability provides an excellent capacity retention of the specific capacity upon cycling.
Journal: Electrochimica Acta - Volume 52, Issue 24, 1 August 2007, Pages 7035–7041